Comet parameter: explicit_deltacn

  • This parameter controls whether or not Comet reports the deltaCn value calculated between the top two peptides ("explicit_deltacn = 1") or between the top peptide and the first dissimilar peptide (default behavior, "explicit_deltacn = 0").
  • The deltaCn score is the normalized difference between two cross-correlation scores. So deltaCn between the top two peptides is calculated as "(xcorr1 - xcorr2) / xcorr1" where xcorr1 is the top scoring peptide and xcorr2 is the second best scoring peptide.
  • However, there are cases were the top two (or top N) scoring peptides are very similar. They may be different modified forms of the same peptide e.g. DLRS*TWDK and DLRST*WDK. In this case, the deltaCn score will be very small because the two peptides are very similar and will have very similar xcorr scores.
  • To mitigate this issue of reporting the deltaCn score for similar peptides, Comet by default performs a crude sequence similarity analysis and reports the deltaCn score as the difference between the top scoring peptide and the first dissimilar peptide. This is the default behavior.
  • This parameter was added to ignore the similarity analysis and always report deltaCn as the normalized difference between the top two xcorr scores.
  • To keep the default behavior of using similarity analysis, set this parameter to "0".
  • To calculate deltaCn between the top two scoring peptides even if their sequences are similar, set this parameter to "1".

Example:
explicit_deltacn = 0
explicit_deltacn = 1